Mechanistic study on the reaction of pinB-BMes<sub>2</sub>with alkynes based on experimental investigation and DFT calculations: gradual change of mechanism depending on the substituent
-
- Linlin Wu
- Department of Chemistry
-
- Chiemi Kojima
- Department of Applied Chemistry
-
- Ka-Ho Lee
- Department of Chemistry
-
- Shogo Morisako
- Department of Molecular and Macromolecular Chemistry
-
- Zhenyang Lin
- Department of Chemistry
-
- Makoto Yamashita
- Department of Molecular and Macromolecular Chemistry
説明
<p>Combination of kinetic and DFT studies revealed a subtle balance for substituent effect toward the regioselectivity of the product in metal-free and base-catalyzed diboration of arylacetylenes.</p>
収録刊行物
-
- Chemical Science
-
Chemical Science 12 (28), 9806-9815, 2021
Royal Society of Chemistry (RSC)
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1360857593798651392
-
- ISSN
- 20416539
- 20416520
-
- 資料種別
- journal article
-
- データソース種別
-
- Crossref
- KAKEN
- OpenAIRE
