Synthesis and characterization of a range of POSS imides

書誌事項

公開日
2012-01
権利情報
  • https://www.elsevier.com/tdm/userlicense/1.0/
DOI
  • 10.1016/j.dyepig.2011.05.028
公開者
Elsevier BV

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説明

Abstract The microwave condensation of mono-amino functionalised polyhedral oligomeric silsesquioxane (POSS) with a range of mono- and bis-anhydrides yielded the corresponding POSS imide compounds, which were characterized by UV–Vis and fluorescence spectrophotometry. The perylene POSS imide derivative was further characterized by single crystal X-ray crystallography. The naphthyl POSS bis/monoimide exhibited extremely weak fluorescence, whilst the perylene POSS bis-imide displayed particularly strong fluorescence, with a quantum yield approaching unity.

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