Good piezoelectricity of self-polarized thick epitaxial (K,Na)NbO3 films grown below the Curie temperature (240 °C) using a hydrothermal method

  • Akinori Tateyama
    Department of Materials Science and Engineering, Tokyo Institute of Technology 1 , Yokohama 226-8502, Japan
  • Yoshiharu Ito
    Department of Materials Science and Engineering, Tokyo Institute of Technology 1 , Yokohama 226-8502, Japan
  • Yoshiko Nakamura
    Department of Materials Science and Engineering, Tokyo Institute of Technology 1 , Yokohama 226-8502, Japan
  • Takao Shimizu
    Department of Materials Science and Engineering, Tokyo Institute of Technology 1 , Yokohama 226-8502, Japan
  • Yuichiro Orino
    Department of Electrical and Electronic Engineering, Tokyo Institute of Technology 3 , Yokohama 226-8502, Japan
  • Minoru Kurosawa
    Department of Electrical and Electronic Engineering, Tokyo Institute of Technology 3 , Yokohama 226-8502, Japan
  • Hiroshi Uchida
    Department of Materials and Life Sciences, Sophia University 4 , Tokyo 102-8554, Japan
  • Takahisa Shiraishi
    Department of Institute for Materials Research, Tohoku University 5 , Sendai 980-8577, Japan
  • Takanori Kiguchi
    Department of Institute for Materials Research, Tohoku University 5 , Sendai 980-8577, Japan
  • Toyohiko J. Konno
    Department of Institute for Materials Research, Tohoku University 5 , Sendai 980-8577, Japan
  • Takeshi Yoshimura
    Department of Physics and Electronics, Osaka Prefecture University 6 , Osaka 599-8531, Japan
  • Hiroshi Funakubo
    Department of Materials Science and Engineering, Tokyo Institute of Technology 1 , Yokohama 226-8502, Japan

抄録

<jats:p>Using a hydrothermal method, (K0.88Na0.12)NbO3 films were deposited at 240 °C on (100) cSrRuO3//(100)SrTiO3 substrates. Moreover, without any poling treatment, direct and inverse transverse piezoelectric coefficients, e31,f, near 0 kV/cm were approximately −5.0 C/m2 for the as-deposited film. This value was nearly unchanged following the application of an electric field and poling treatment, suggesting that as-deposited films are almost in a fully self-polarized state without the application of an electric field. As-deposited films with a thickness of up to 22 μm showed constant piezoelectricity without any poling treatment. The films did not crack or peel because of substrates due to the small thermal strain originating from the low deposition temperature. The figures of merit (FOM) for the vibration energy harvester [FOM = e31,f2/(ε0εr)] and sensor [FOM = e31,f/(ε0εr)] were estimated to be good at 32.8 GPa and –5.9 GV/m, respectively, primarily because of the low relative dielectric constant of ∼110. Furthermore, the piezoelectric voltage coefficient g31 [= d31/(ε0εr)] was estimated and demonstrated a high value of 0.073 Vm/N.</jats:p>

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