Recent Progress and Challenges toward Highly Stable Nonfullerene Acceptor‐Based Organic Solar Cells
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- Yiwen Wang
- School of Engineering and Materials Science Queen Mary University of London London E1 4NS UK
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- Jinho Lee
- Max‐Planck‐Institut für Kohlenforschung Kaiser‐Wilhelm‐Platz 1 Mülheim an der Ruhr 45470 Germany
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- Xueyan Hou
- School of Engineering and Materials Science Queen Mary University of London London E1 4NS UK
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- Chiara Labanti
- Department of Physics and Center for Processable Electronics Imperial College London London SW7 2AZ UK
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- Jun Yan
- Department of Physics and Center for Processable Electronics Imperial College London London SW7 2AZ UK
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- Eva Mazzolini
- School of Engineering and Materials Science Queen Mary University of London London E1 4NS UK
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- Amber Parhar
- Department of Physics and Center for Processable Electronics Imperial College London London SW7 2AZ UK
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- Jenny Nelson
- Department of Physics and Center for Processable Electronics Imperial College London London SW7 2AZ UK
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- Ji‐Seon Kim
- Department of Physics and Center for Processable Electronics Imperial College London London SW7 2AZ UK
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- Zhe Li
- School of Engineering and Materials Science Queen Mary University of London London E1 4NS UK
説明
<jats:title>Abstract</jats:title><jats:p>Organic solar cells (OSCs) based on nonfullerene acceptors (NFAs) have made significant breakthrough in their device performance, now achieving a power conversion efficiency of ≈18% for single junction devices, driven by the rapid development in their molecular design and device engineering in recent years. However, achieving long‐term stability remains a major challenge to overcome for their commercialization, due in large part to the current lack of understanding of their degradation mechanisms as well as the design rules for enhancing their stability. In this review, the recent progress in understanding the degradation mechanisms and enhancing the stability of high performance NFA‐based OSCs is a specific focus. First, an overview of the recent advances in the molecular design and device engineering of several classes of high performance NFA‐based OSCs for various targeted applications is provided, before presenting a critical review of the different degradation mechanisms identified through photochemical‐, photo‐, and morphological degradation pathways. Potential strategies to address these degradation mechanisms for further stability enhancement, from molecular design, interfacial engineering, and morphology control perspectives, are also discussed. Finally, an outlook is given highlighting the remaining key challenges toward achieving the long‐term stability of NFA‐OSCs.</jats:p>
収録刊行物
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- Advanced Energy Materials
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Advanced Energy Materials 11 (5), 2020-12-27
Wiley