Synthesis of Oxazoline and Oxazole Derivatives by Hypervalent-Iodine-Mediated Oxidative Cycloaddition Reactions

DOI PDF 被引用文献1件
  • Akira Yoshimura
    Department of Chemistry and Biochemistry, University of Minnesota Duluth
  • Akio Saito
    Division of Applied Chemistry, Institute of Engineering, Tokyo University of Agriculture and Technology
  • Viktor V. Zhdankin
    Department of Chemistry and Biochemistry, University of Minnesota Duluth
  • Mekhman S. Yusubov
    Research School of Chemistry and Applied Biomedical Sciences, The Tomsk Polytechnic University

書誌事項

公開日
2020-05-18
DOI
  • 10.1055/s-0040-1707122
公開者
Georg Thieme Verlag KG

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説明

<jats:p>Organohypervalent iodine reagents are widely used for the preparation of various oxazolines, oxazoles, isoxazolines, and isoxazoles. In the formation of these heterocyclic compounds, hypervalent iodine species can serve as the activating reagents for various substrates, as well as the heteroatom donor reagents. In recent research, both chemical and electrochemical approaches toward generation of hypervalent iodine species have been utilized. The in situ generated active species can react with appropriate substrates to give the corresponding heterocyclic products. In this short review, we summarize the hypervalent-iodine­-mediated preparation of oxazolines, oxazoles, isoxazolines, and isoxazoles starting from various substrates.</jats:p><jats:p>1 Introduction</jats:p><jats:p>2 Synthesis of Oxazolines</jats:p><jats:p>3 Synthesis of Oxazoles</jats:p><jats:p>4 Synthesis of Isoxazolines</jats:p><jats:p>5 Synthesis of Isoxazoles</jats:p><jats:p>6 Conclusion</jats:p>

収録刊行物

  • Synthesis

    Synthesis 52 (16), 2299-2310, 2020-05-18

    Georg Thieme Verlag KG

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