Control of intramolecular singlet fission in a pentacene dimer by hydrostatic pressure

DOI Web Site 49 References
  • Tomokazu Kinoshita
    Department of Chemistry, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8551, Japan
  • Shunta Nakamura
    Department of Chemistry, Faculty of Science and Technology, Keio University, Yokohama, Kanagawa 223-8522, Japan
  • Makoto Harada
    Department of Chemistry, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8551, Japan
  • Taku Hasobe
    Department of Chemistry, Faculty of Science and Technology, Keio University, Yokohama, Kanagawa 223-8522, Japan
  • Gaku Fukuhara
    Department of Chemistry, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8551, Japan

Abstract

<jats:p>We investigated singlet fission (SF) effects of a biphenyl-bridged pentacene dimer upon hydrostatic pressurization, revealing that the desolvation process in polar solvents plays an important role in the SF dynamics under high pressure.</jats:p>

Journal

  • Chemical Science

    Chemical Science 14 (12), 3293-3301, 2023

    Royal Society of Chemistry (RSC)

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