Indolo[3,2,1‐<i>jk</i>]carbazole Embedded Multiple‐Resonance Fluorophors for Narrowband Deep‐blue Electroluminescence with EQE≈34.7 % and CIE<sub>y</sub>≈0.085

  • Jinbei Wei
    Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 P. R. China
  • Chen Zhang
    Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education Department of Chemistry Tsinghua University Beijing 100084 P. R. China
  • Dongdong Zhang
    Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education Department of Chemistry Tsinghua University Beijing 100084 P. R. China
  • Yuewei Zhang
    Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education Department of Chemistry Tsinghua University Beijing 100084 P. R. China
  • Ziyang Liu
    Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education Department of Chemistry Tsinghua University Beijing 100084 P. R. China
  • Zhiqiang Li
    JiHua Laboratory Foshan 528200 Guangdong Province P. R. China
  • Gui Yu
    Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 P. R. China
  • Lian Duan
    Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education Department of Chemistry Tsinghua University Beijing 100084 P. R. China

抄録

<jats:title>Abstract</jats:title><jats:p>Multiple‐resonance (MR) organic emitters bearing small full‐width at half‐maximum (FWHMs) are of general interest in organic light‐emitting diodes. Indolo[3,2,1‐<jats:italic>jk</jats:italic>]carbazole (ICz) embedded MR‐fluorophors have demonstrated extremely small FWHMs, yet in the violet region with low electroluminescence efficiency. Herein, a strategic implementation of ICz subunits into MR fluorophors is proposed by taking advantage of the synergetic effect of <jats:italic>para</jats:italic>‐positioned nitrogen atoms to enhance electronic coupling to decrease emitting energy gap. Deep blue emitters peaking at 441 and 447 nm with FWHMs of only 18 and 21 nm are thereof obtained, respectively, accompanied by ≈90 % photo‐luminance quantum yields. With the assistance of a thermally activated delayed fluorescence sensitizer to recycle excitons, the corresponding narrowband electroluminescent devices show unprecedent high maximum external quantum efficiencies of 32.0 % and 34.7 % with CIE<jats:sub>y</jats:sub> of 0.10 and 0.085, respectively.</jats:p>

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