Electronic structure and bonding in endohedral Zintl clusters

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  • John E. McGrady
    Physical and Theoretical Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, OX1 3QZ, UK
  • Florian Weigend
    Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften, Philipps University Marburg, Hans-Meerwein-Straße 4, 35043 Marburg, Germany
  • Stefanie Dehnen
    Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften, Philipps University Marburg, Hans-Meerwein-Straße 4, 35043 Marburg, Germany

Abstract

<jats:p>Despite many different views on the bonding in endohedral Zintl clusters, the relationship between their valence electron count and their structure and bonding patterns is much more uniform than previously anticipated, as highlighted in this article.</jats:p>

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