RAFT aqueous emulsion polymerization of methyl methacrylate: observation of unexpected constraints when employing a non-ionic steric stabilizer block

DOI Web Site 1 Citations
  • Derek H. H. Chan
    Dainton Building, Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, South Yorkshire, S3 7HF, UK
  • Amy A. Cockram
    Dainton Building, Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, South Yorkshire, S3 7HF, UK
  • Rebecca R. Gibson
    Dainton Building, Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, South Yorkshire, S3 7HF, UK
  • Emily L. Kynaston
    Syngenta, Jealott's Hill International Research Centre, Bracknell, Berkshire, RG42 6EY, UK
  • Christopher Lindsay
    Syngenta, Jealott's Hill International Research Centre, Bracknell, Berkshire, RG42 6EY, UK
  • Philip Taylor
    Syngenta, Jealott's Hill International Research Centre, Bracknell, Berkshire, RG42 6EY, UK
  • Steven P. Armes
    Dainton Building, Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, South Yorkshire, S3 7HF, UK

Abstract

<jats:p>Using a <jats:italic>non-ionic</jats:italic> steric stabilizer for the RAFT aqueous emulsion polymerization of methyl methacrylate leads to flocculated nanoparticles when targeting DPs > 100; there is no such constraint when employing an <jats:italic>anionic</jats:italic> stabilizer block.</jats:p>

Journal

  • Polymer Chemistry

    Polymer Chemistry 12 (40), 5760-5769, 2021

    Royal Society of Chemistry (RSC)

Citations (1)*help

See more

Details 詳細情報について

Report a problem

Back to top