Reversible crosslinking and fast stress relaxation in dynamic polymer networks <i>via</i> transalkylation using 1,4-diazabicyclo[2.2.2] octane
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- Eveline E. L. Maassen
- Supramolecular Polymer Chemistry group
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- Johan P. A. Heuts
- Supramolecular Polymer Chemistry group
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- Rint P. Sijbesma
- Supramolecular Polymer Chemistry group
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説明
<p>A dynamic covalent network using transalkylation of benzyl-DABCO crosslinkers features fast relaxation with a very strong temperature dependence. The network is de-crosslinked by an excess of DABCO.</p>
収録刊行物
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- Polymer Chemistry
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Polymer Chemistry 12 (25), 3640-3649, 2021
Royal Society of Chemistry (RSC)