Construction of Structure-Controlled Perovskite Ultra-Thin Layers on Au(100) Single-Crystal Surface <i>via</i> Self-Assembled Monolayer of 4-Aminothiophenol

  • Mami Takahari
    Division of Chemistry, Graduate School of Humanities and Sciences, Ochanomizu University, 2-1-1 Ohtsuka, Bunkyo-ku, Tokyo 112-8610 , Japan
  • Toshihiro Kondo
    Division of Chemistry, Graduate School of Humanities and Sciences, Ochanomizu University, 2-1-1 Ohtsuka, Bunkyo-ku, Tokyo 112-8610 , Japan

書誌事項

公開日
2020-10-09
権利情報
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1246/bcsj.20200271
公開者
Oxford University Press (OUP)

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説明

<jats:title>Abstract</jats:title> <jats:p>In order to control a crystal configuration of MAPbBr3 (MA = CH3NH3+) perovskite ultra-thin layers, the Au(100) single-crystal, the self-assembled monolayer (SAM) of 4-aminothiophenol (4-ATP), and the layer-by-layer alternating immersion were employed as a substrate, a linker between the perovskite thin layer and gold substrate, and a preparation method, respectively. Structure and crystal configuration of the constructed MAPbBr3 perovskite ultra-thin layers on 4-ATP SAM modified Au(100) were investigated by X-ray photoelectron spectroscopy (XPS), scanning tunneling microscopy (STM), and grazing incidence surface X-ray diffraction (GISXRD). As a result, we succeeded to construct the structure-controlled MAPbBr3 perovskite ultra-thin layers on the 4-ATP SAM modified Au(100) surface with an atomic dimension.</jats:p>

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