Covalent organic frameworks comprising cobalt porphyrins for catalytic CO <sub>2</sub> reduction in water
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- Song Lin
- Department of Chemistry, University of California, Berkeley, CA 94720, USA.
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- Christian S. Diercks
- Department of Chemistry, University of California, Berkeley, CA 94720, USA.
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- Yue-Biao Zhang
- Department of Chemistry, University of California, Berkeley, CA 94720, USA.
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- Nikolay Kornienko
- Department of Chemistry, University of California, Berkeley, CA 94720, USA.
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- Eva M. Nichols
- Department of Chemistry, University of California, Berkeley, CA 94720, USA.
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- Yingbo Zhao
- Department of Chemistry, University of California, Berkeley, CA 94720, USA.
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- Aubrey R. Paris
- Department of Chemistry, University of California, Berkeley, CA 94720, USA.
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- Dohyung Kim
- Department of Materials Science and Engineering, University of California, Berkeley, CA 94720, USA.
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- Peidong Yang
- Department of Chemistry, University of California, Berkeley, CA 94720, USA.
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- Omar M. Yaghi
- Department of Chemistry, University of California, Berkeley, CA 94720, USA.
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- Christopher J. Chang
- Department of Chemistry, University of California, Berkeley, CA 94720, USA.
書誌事項
- 公開日
- 2015-09-11
- 権利情報
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- http://www.sciencemag.org/about/science-licenses-journal-article-reuse
- DOI
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- 10.1126/science.aac8343
- 公開者
- American Association for the Advancement of Science (AAAS)
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説明
<jats:title>Improving cobalt catalysts</jats:title> <jats:p> Tethering molecular catalysts together is a tried and trusted method for making them easier to purify and reuse. Lin <jats:italic>et al.</jats:italic> now show that the assembly of a covalent organic framework (COF) structure can also improve fundamental catalytic performance. They used cobalt porphyrin complexes as building blocks for a COF. The resulting material showed greatly enhanced activity for the aqueous electrochemical reduction of CO <jats:sub>2</jats:sub> to CO. </jats:p> <jats:p> <jats:italic>Science</jats:italic> , this issue p. <jats:related-article xmlns:xlink="http://www.w3.org/1999/xlink" ext-link-type="doi" issue="6253" page="1208" related-article-type="in-this-issue" vol="349" xlink:href="10.1126/science.aac8343">1208</jats:related-article> </jats:p>
収録刊行物
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- Science
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Science 349 (6253), 1208-1213, 2015-09-11
American Association for the Advancement of Science (AAAS)
