Multiwavelength excitation Raman scattering study of polycrystalline kesterite Cu2ZnSnS4 thin films

  • M. Dimitrievska
    Catalonia Institute for Energy Research (IREC) 1 , C. Jardins de les Dones de Negre 1, 08930 Sant Adrià del Besos, Barcelona, Spain
  • A. Fairbrother
    Catalonia Institute for Energy Research (IREC) 1 , C. Jardins de les Dones de Negre 1, 08930 Sant Adrià del Besos, Barcelona, Spain
  • X. Fontané
    Catalonia Institute for Energy Research (IREC) 1 , C. Jardins de les Dones de Negre 1, 08930 Sant Adrià del Besos, Barcelona, Spain
  • T. Jawhari
    Centres Científics i Technologies CCiTUB, Universitat de Barcelona 2 , C. Lluis Sole i Sabarís 1, 08028 Barcelona, Spain
  • V. Izquierdo-Roca
    Catalonia Institute for Energy Research (IREC) 1 , C. Jardins de les Dones de Negre 1, 08930 Sant Adrià del Besos, Barcelona, Spain
  • E. Saucedo
    Catalonia Institute for Energy Research (IREC) 1 , C. Jardins de les Dones de Negre 1, 08930 Sant Adrià del Besos, Barcelona, Spain
  • A. Pérez-Rodríguez
    Catalonia Institute for Energy Research (IREC) 1 , C. Jardins de les Dones de Negre 1, 08930 Sant Adrià del Besos, Barcelona, Spain

書誌事項

公開日
2014-01-13
DOI
  • 10.1063/1.4861593
公開者
AIP Publishing

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説明

<jats:p>This work presents a complete analysis of all Raman active modes of Cu2ZnSnS4 measuring with six different excitation wavelengths from near infrared to ultraviolet. Simultaneous fitting of spectra allowed identification of 18 peaks from device grade layers with composition close to stoichiometry that are attributed to the 27 optical modes theoretically expected for this crystalline structure, including detection of 5 peaks not observed previously, but theoretically predicted. Resonance effects are assumed to explain the observed increase in intensity of weak modes for near infrared and ultraviolet excitations. These results are particularly relevant for experimental discrimination of Raman modes related to secondary phases.</jats:p>

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