Solvent-induced stabilization of the naphthalene anion by water molecules: A negative cluster ion photoelectron spectroscopic study

  • Svetlana A. Lyapustina
    Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218
  • Shoujun Xu
    Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218
  • J. Michael Nilles
    Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218
  • Kit H. Bowen
    Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218

書誌事項

公開日
2000-04-15
DOI
  • 10.1063/1.481237
公開者
AIP Publishing

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説明

<jats:p>We show that (a) only a single water molecule is needed to stabilize the naphthalene anion, (b) the EAa of naphthalene is −0.20 eV, in agreement with determinations by electron transmission spectroscopy, (c) the energetics are consistent with the number of waters required to stabilize the naphthalene anion, and (d) the excess electron is located on the naphthalene moiety of Nph1−(H2O)n.</jats:p>

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