Solvent-induced stabilization of the naphthalene anion by water molecules: A negative cluster ion photoelectron spectroscopic study
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- Svetlana A. Lyapustina
- Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218
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- Shoujun Xu
- Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218
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- J. Michael Nilles
- Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218
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- Kit H. Bowen
- Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218
書誌事項
- 公開日
- 2000-04-15
- DOI
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- 10.1063/1.481237
- 公開者
- AIP Publishing
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説明
<jats:p>We show that (a) only a single water molecule is needed to stabilize the naphthalene anion, (b) the EAa of naphthalene is −0.20 eV, in agreement with determinations by electron transmission spectroscopy, (c) the energetics are consistent with the number of waters required to stabilize the naphthalene anion, and (d) the excess electron is located on the naphthalene moiety of Nph1−(H2O)n.</jats:p>
収録刊行物
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- The Journal of Chemical Physics
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The Journal of Chemical Physics 112 (15), 6643-6648, 2000-04-15
AIP Publishing
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詳細情報 詳細情報について
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- CRID
- 1361137045301276160
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- DOI
- 10.1063/1.481237
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- ISSN
- 10897690
- 00219606
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- データソース種別
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- Crossref