Amides as Weak Coordinating Groups in Proximal C–H Bond Activation

  • Riki Das
    Department of Chemistry Indian Institute of Science Education and Research Bhopal Bhopal Bypass Road, Bhauri 462066 Bhopal MP India
  • Gangam Srikanth Kumar
    Department of Chemistry Indian Institute of Science Education and Research Bhopal Bhopal Bypass Road, Bhauri 462066 Bhopal MP India
  • Manmohan Kapur
    Department of Chemistry Indian Institute of Science Education and Research Bhopal Bhopal Bypass Road, Bhauri 462066 Bhopal MP India

書誌事項

公開日
2017-08-08
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/ejoc.201700546
公開者
Wiley

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説明

<jats:p>Site selectivity is an inherent challenge in C–H functionalization reactions. The most intensively sought‐after approaches have involved the employment of Lewis‐basic coordinating groups to direct a metal to a proximal site, in the process generating a metallacycle capable of further organometallic reactivity. In the recent years considerable effort has been directed towards the development of new transformations involving transition‐metal‐mediated C–H functionalization directed by weakly coordinating groups. This microreview focuses on the role and utility of amides and anilides in directed, proximal C–H bond functionalization reactions.</jats:p>

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