Structural characterization of milled mesophase pitch-based carbon fibers

書誌事項

公開日
1998-11
権利情報
  • https://www.elsevier.com/tdm/userlicense/1.0/
DOI
  • 10.1016/s0008-6223(98)00157-2
公開者
Elsevier BV

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説明

The microstructure of milled mesophase pitch-based carbon fibers (mMPCFs) that have been developed as an anode material for Li ion batteries has been studied as a function of heat treatment temperature (HTT) mainly by Raman spectroscopy, and the results obtained are compared with those by X-ray diffraction (XRD) and scanning electron microscopy (SEM) observations. As a functional material, SEM measurements indicate that these mMPCFs have a characteristic controlled cross-sectional morphology like a bamboo skin structure which is different to that of conventional mesophase pitch-based carbon fibers for composite use. The mMPCFs with HTT>2000°C clearly show the 110 and 112 XRD peaks indicating the development of three-dimensional graphite stacking from a turbostratic structure. The mMPCFs heat-treated at temperatures >2000°C contain larger domain sizes along their longitudinal surface that those along the periphery of the fiber, as demonstrated by microprobe Raman scattering experiments. These mMPCFs could be promising as a functional material for applications, such as to Li ion batteries, but not for composite applications.

収録刊行物

  • Carbon

    Carbon 36 (11), 1633-1641, 1998-11

    Elsevier BV

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