The rheology of hard sphere suspensions at arbitrary volume fractions: An improved differential viscosity model
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- Carlos I. Mendoza
- Universidad Nacional Autónoma de México 1 Instituto de Investigaciones en Materiales, , Apdo. Postal 70-360, 04510 México Distrito Federal, Mexico
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- I. Santamaría-Holek
- Universidad Nacional Autónoma de México 2 Facultad de Ciencias, , Circuito Exterior de Ciudad Universitaria, 04510 México Distrito Federal, Mexico
説明
<jats:p>We propose a simple and general model accounting for the dependence of the viscosity of a hard sphere suspension at arbitrary volume fractions. The model constitutes a continuum-medium description based on a recursive-differential method where correlations between the spheres are introduced through an effective volume fraction. In contrast to other differential methods, the introduction of the effective volume fraction as the integration variable implicitly considers interactions between the spheres of the same recursive stage. The final expression for the viscosity scales with this effective volume fraction, which allows constructing a master curve that contains all the experimental situations considered. The agreement of our expression for the viscosity with experiments at low- and high-shear rates and in the high-frequency limit is remarkable for all volume fractions.</jats:p>
収録刊行物
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- The Journal of Chemical Physics
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The Journal of Chemical Physics 130 (4), 2009-01-27
AIP Publishing
