INFRARED SPECTRA OF GASES CHEMISORBED ON ZINC OXIDE: I. CO AND CO<sub>2</sub>

DOI Web Site 被引用文献5件

書誌事項

公開日
1961-03-01
権利情報
  • http://www.nrcresearchpress.com/page/about/CorporateTextAndDataMining
DOI
  • 10.1139/v61-064
公開者
Canadian Science Publishing

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説明

<jats:p> The infrared spectra of CO and CO<jats:sub>2</jats:sub> adsorbed on zinc oxide have been observed in the region 2–9 µ. The results show that CO does not exist as such on the surface at 155 °C, but is immediately oxidized to CO<jats:sub>2</jats:sub>. There is no evidence for carbonate formation in the adsorption of CO, the spectra corresponding to structures of the carboxylate type. A band is observed at 2174 cm<jats:sup>−1</jats:sup> for CO at 25 °C which may correspond to dipole interaction or to an oxidation step. </jats:p>

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