Design of Molecular and Ionic Complexes of Fullerene C<sub>60</sub> with Metal(II) Octaethylporphyrins, M<sup>II</sup>OEP (M = Zn, Co, Fe, and Mn) Containing Coordination M−N(ligand) and M−C(C<sub>60</sub><sup>−</sup>) Bonds

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  • Dmitri V. Konarev
    Institute of Problems of Chemical Physics RAS, Chernogolovka, Russia, Institute of Solid State Physics RAS, Chernogolovka, Moscow Region, 142432, Russia, and Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan
  • Salavat S. Khasanov
    Institute of Problems of Chemical Physics RAS, Chernogolovka, Russia, Institute of Solid State Physics RAS, Chernogolovka, Moscow Region, 142432, Russia, and Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan
  • Gunzi Saito
    Institute of Problems of Chemical Physics RAS, Chernogolovka, Russia, Institute of Solid State Physics RAS, Chernogolovka, Moscow Region, 142432, Russia, and Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan
  • Rimma N. Lyubovskaya
    Institute of Problems of Chemical Physics RAS, Chernogolovka, Russia, Institute of Solid State Physics RAS, Chernogolovka, Moscow Region, 142432, Russia, and Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

説明

The formation of coordination bonds between metalloporphyrins and N-containing ligands or C60•− was used to prepare molecular and ionic complexes of C60 with metal(II) octaethylporphyrins: {MIIOEP·DABCO}·C60·(Solvent) (M = Zn (4) and Co (5)); {(MDABCO+)·MIIOEP}·(C60•−)·(Solvent) (M = Zn (6), Fe (8), and Mn (9)), (MQ+)·{CoIIOEP·(C60−)}·C6H4Cl2 (10) and {(DMETEP+)·ZnIIOEP}·(C60•−)·(C60)0.5·C6H4Cl2 (12). New molecular complexes of C60 with ligand free metalloporphyrins MIIOEP·C60·(Solvent)1.5 (M = Zn (1), Co (2), and Fe (3)) were also obtained for comparison. Complexes 1−3 contain alternating pairs of C60 and MIIOEP molecules, whereas isostructural complexes 4−10 contain porphyrin channels accommodating zigzag fullerene chains. Complex 12 is a first example of fullerene complex containing simultaneously charged and neutral fullerene species arranged in zigzag chains and cavities formed by two (DMETEP+)·ZnOEP units. The coordination of DABCO, MDABCO+, DMETEP+, C60, and C60•− to MIIOEP was studied and their co...

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