π‐Conjugated Macrocycles Bearing Angle‐Strained Alkynes

DOI HANDLE Web Site Web Site PubMed 被引用文献10件 参考文献391件
  • Koji Miki
    Department of Energy and Hydrocarbon Chemistry Graduate School of Engineering Kyoto University Katsura Nishikyo-ku Kyoto 615–8510 Japan
  • Kouichi Ohe
    Department of Energy and Hydrocarbon Chemistry Graduate School of Engineering Kyoto University Katsura Nishikyo-ku Kyoto 615–8510 Japan
  • 三木, 康嗣
  • 大江, 浩一
  • 60422979

この論文をさがす

説明

<jats:title>Abstract</jats:title><jats:p>Angle‐strained alkyne‐containing π‐conjugated macrocycles are attractive compounds both in functional materials chemistry and biochemistry. Their interesting reactivity as well as photophysical and supramolecular properties have been revealed in the past three decades. This review highlights the recent advances in angle‐strained alkyne‐containing π‐conjugated macrocycles, especially their synthetic methods, the bond angles of alkynes (∠<jats:sub>sp</jats:sub> at C≡C−C), and their functions. The theoretical and experimental research on cyclo[<jats:italic>n</jats:italic>]carbons and <jats:italic>para</jats:italic>‐cyclophynes consisting of ethynylenes and <jats:italic>para</jats:italic>‐phenylenes are mainly summarized. Related macrocycles bearing other linkers, such as <jats:italic>ortho</jats:italic>‐phenylenes, <jats:italic>meta</jats:italic>‐phenylenes, heteroaromatics, biphenyls, extended aromatics, are also overviewed. Bond angles of strained alkynes in π‐conjugated macrocycles, which are generable, detectable, and isolable, are summarized at the end of this review.</jats:p>

収録刊行物

被引用文献 (10)*注記

もっと見る

参考文献 (391)*注記

もっと見る

関連プロジェクト

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ