Preparation and Properties of Gold Complexes with TTF Dithiolato Ligands

DOI HANDLE Web Site 3 Citations
  • Yohji Misaki
    a Department of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida , Kyoto , 606-8501 , Japan
  • Yoshihiro Tani
    a Department of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida , Kyoto , 606-8501 , Japan
  • Masateru Taniguchi
    a Department of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida , Kyoto , 606-8501 , Japan
  • Tatsuyuki Maitani
    a Department of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida , Kyoto , 606-8501 , Japan
  • Kazuyoshi Tanaka
    a Department of Molecular Engineering , Graduate School of Engineering, Kyoto University , Yoshida , Kyoto , 606-8501 , Japan
  • Klaus Bechgaard
    b Department of Solid State Physics , Risø National Laboratory , P. O. Box 49, Roskilde , DK-4000 , Denmark
  • 90155119

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Description

Several gold(III) complexes with TTF dithiolato ligands have been prepared as the tetrahexylammonium salts. The cyclic voltammograms in DMF showed two or three pairs of redox waves. X-Ray structure analysis of Ph 4 P.Au(eodt) 2 .(DMF) 2 reveals that the Au(codt) 2 anion takes a significantly folded chair conformation. Charge-transfer salts of Au(dt) 2 derivatives with TCNQ showed high conductivity (σ rt = 10 0 -10 1 S cm - on a compressed pellet).

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