Dinitrogen Fixation: Rationalizing Strategies Utilizing Molecular Complexes

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  • Fabio Masero
    Department of Chemistry and Applied Biosciences Laboratory of Inorganic Chemistry ETH Zürich Vladimir Prelog Weg 1–5 8093 Zürich Switzerland
  • Marie A. Perrin
    Department of Chemistry and Applied Biosciences Laboratory of Inorganic Chemistry ETH Zürich Vladimir Prelog Weg 1–5 8093 Zürich Switzerland
  • Subal Dey
    Department of Chemistry and Applied Biosciences Laboratory of Inorganic Chemistry ETH Zürich Vladimir Prelog Weg 1–5 8093 Zürich Switzerland
  • Victor Mougel
    Department of Chemistry and Applied Biosciences Laboratory of Inorganic Chemistry ETH Zürich Vladimir Prelog Weg 1–5 8093 Zürich Switzerland

書誌事項

公開日
2020-12-29
権利情報
  • http://creativecommons.org/licenses/by-nc-nd/4.0/
DOI
  • 10.1002/chem.202003134
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>Dinitrogen (N<jats:sub>2</jats:sub>) is the most abundant gas in Earth's atmosphere, but its inertness hinders its use as a nitrogen source in the biosphere and in industry. Efficient catalysts are hence required to ov. ercome the high kinetic barriers associated to N<jats:sub>2</jats:sub> transformation. In that respect, molecular complexes have demonstrated strong potential to mediate N<jats:sub>2</jats:sub> functionalization reactions under mild conditions while providing a straightforward understanding of the reaction mechanisms. This Review emphasizes the strategies for N<jats:sub>2</jats:sub> reduction and functionalization using molecular transition metal and actinide complexes according to their proposed reaction mechanisms, distinguishing complexes inducing cleavage of the N≡N bond before (dissociative mechanism) or concomitantly with functionalization (associative mechanism). We present here the main examples of stoichiometric and catalytic N<jats:sub>2</jats:sub> functionalization reactions following these strategies.</jats:p>

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