<i>p</i>-type conductivity in CuCr1−xMgxO2 films and powders

  • R. Nagarajan
    Department of Chemistry and Center for Advanced Materials Research, Oregon State University, Corvallis, Oregon 97331
  • A. D. Draeseke
    Department of Physics and Center for Advanced Materials Research, Oregon State University, Corvallis, Oregon 97331
  • A. W. Sleight
    Department of Chemistry and Center for Advanced Materials Research, Oregon State University, Corvallis, Oregon 97331
  • J. Tate
    Department of Physics and Center for Advanced Materials Research, Oregon State University, Corvallis, Oregon 97331

書誌事項

公開日
2001-06-15
DOI
  • 10.1063/1.1372636
公開者
AIP Publishing

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説明

<jats:p>CuCr 1−x Mg x O 2 , a wide band gap semiconductor with the delafossite structure, has been synthesized in bulk and thin-film form. Bulk undoped CuCrO2 is almost black and has moderate conductivity with p-type carriers. Upon doping with 5% Mg, the conductivity increases by a factor of 1000. In films, the best p-type conductivity is 220 S cm−1 in CuCr0.95Mg0.05O2, a factor of 7 higher than previously reported for Cu-based p-type delafossites. Undoped films have a conductivity of order 1 S cm−1. Films are usually polycrystalline on amorphous substrates, but undoped films can be c-axis oriented if deposited at or above 650 °C. Optical and ultraviolet transmission data indicate a direct band gap of 3.1 eV.</jats:p>

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