Chemistry on a Half‐Shell: Synthesis and Derivatization of Buckybowls
書誌事項
- 公開日
- 2011-02-07
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/ejoc.201001585
- 公開者
- Wiley
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説明
<jats:title>Abstract</jats:title><jats:p>Buckybowls, bowl‐shaped polycyclic aromatic hydrocarbons structurally related to fullerenes, represent a class of hydrocarbons with unique properties and a potential for application as novel materials. This review outlines the development of the practical preparations of buckybowls, starting with the original synthesis of corannulene achieved in 1966. A particular attention is paid to the last decade developments which include construction of large, highly nonplanar molecular networks (molecular clips and tweezers) capable of binding guest molecules of various sizes and shapes. In particular, such molecular clips were proven to form stable supramolecular complexes with fullerenes C<jats:sub>60</jats:sub> and C<jats:sub>70</jats:sub>, both in solution and in the solid state.</jats:p>
収録刊行物
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- European Journal of Organic Chemistry
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European Journal of Organic Chemistry 2011 (9), 1611-1625, 2011-02-07
Wiley