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- Dengxu Wang
- Leibniz-Institut für Katalyse e.V. an der Universität Rostock Albert-Einstein-Strasse 29a 18059 Rostock Germany
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- Johann Klein
- Adhesive Technologies, AR Reactive Systems Henkel AG & Co KGaA Henkelstraße 67 40589 Düsseldorf Germany
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- Esteban Mejía
- Leibniz-Institut für Katalyse e.V. an der Universität Rostock Albert-Einstein-Strasse 29a 18059 Rostock Germany
書誌事項
- 公開日
- 2017-05-15
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/asia.201700304
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>Silicones and silicone rubbers are omnipresent in household and industrial products such as lubricants, coatings, sealants, insulators, medical devices, etc. This plethora of applications arises from their unparalleled properties including hydrophobicity, low surface energy, chemical inertness, extreme temperature stability, elasticity, and biocompatibility. Even though silicones have been known for more than five decades, their chemistry is still far from fully understood. Industrially, the vast majority of processes for their synthesis, transformation, and use are based on rather well established, alas outdated technologies, which are frequently empirical and poorly investigated. This review attempts to summarize the different approaches for the synthesis of silicone rubbers by vulcanization or curing of silicone polymers, the catalysts used, and the corresponding reaction mechanisms. Apart from the well‐known methods (radical, hydrosilylation, and metal‐based condensation), novel approaches such as organo‐ and bio‐catalysis are also addressed.</jats:p>
収録刊行物
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- Chemistry – An Asian Journal
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Chemistry – An Asian Journal 12 (11), 1180-1197, 2017-05-15
Wiley