Raman analysis of monoclinic Cu2SnS3 thin films

  • Dominik M. Berg
    University of Luxembourg, Laboratory for Photovoltaics 1 , 41, rue du Brill, L-4422 Belvaux, Luxembourg
  • Rabie Djemour
    University of Luxembourg, Laboratory for Photovoltaics 1 , 41, rue du Brill, L-4422 Belvaux, Luxembourg
  • Levent Gütay
    University of Luxembourg, Laboratory for Photovoltaics 1 , 41, rue du Brill, L-4422 Belvaux, Luxembourg
  • Susanne Siebentritt
    University of Luxembourg, Laboratory for Photovoltaics 1 , 41, rue du Brill, L-4422 Belvaux, Luxembourg
  • Phillip J. Dale
    University of Luxembourg, Laboratory for Photovoltaics 1 , 41, rue du Brill, L-4422 Belvaux, Luxembourg
  • Xavier Fontane
    Catalonia Institute for Energy Research (IREC) 2 , C. Jardins de les Dones de Negre 1, 08930 Sant Adrià del Besòs, Barcelona, Spain
  • Victor Izquierdo-Roca
    Catalonia Institute for Energy Research (IREC) 2 , C. Jardins de les Dones de Negre 1, 08930 Sant Adrià del Besòs, Barcelona, Spain
  • Alejandro Pérez-Rodriguez
    Catalonia Institute for Energy Research (IREC) 2 , C. Jardins de les Dones de Negre 1, 08930 Sant Adrià del Besòs, Barcelona, Spain

書誌事項

公開日
2012-05-07
DOI
  • 10.1063/1.4712623
公開者
AIP Publishing

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説明

<jats:p>Secondary phases like Cu2SnS3 are major obstacles for kesterite thin film solar cell applications. We prepare Cu2SnS3 using identical annealing conditions as used for the kesterite films. By x-ray diffraction, the crystal structure of Cu2SnS3 was identified as monoclinic. Polarization-dependent Raman investigations allowed the identification of the dominant peaks at 290 cm−1 and 352 cm−1 with the main A′ symmetry vibrational modes from the monoclinic Cu2SnS3 phase. Furthermore, micro-resolved Raman investigations revealed local variations in the spectra that are attributed to a secondary phase (possibly Cu2Sn3S7). This exemplifies the abilities of micro-resolved Raman measurements in the detection of secondary phases.</jats:p>

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