Copper‐Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF<sub>3</sub>‐Containing Alkyl Azides

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<jats:title>Abstract</jats:title><jats:p>A novel copper‐catalyzed intermolecular trifluoromethylazidation of alkenes has been developed under mild reaction conditions. A variety of CF<jats:sub>3</jats:sub>‐containing organoazides were directly synthesized from a wide range of olefins, including activated and unactivated alkenes, and the resulting products can be easily transformed into the corresponding CF<jats:sub>3</jats:sub>‐containing amine derivatives.</jats:p>

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