Supramolecular Chiral Nanoarchitectonics

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  • Katsuhiko Ariga
    WPI‐MANA National Institute for Materials Science 1‐1 Namiki Tsukuba Ibaraki 305‐0044 Japan
  • Taizo Mori
    WPI‐MANA National Institute for Materials Science 1‐1 Namiki Tsukuba Ibaraki 305‐0044 Japan
  • Takashi Kitao
    Department of Advanced Materials Science Graduate School of Frontier Sciences The University of Tokyo 5‐1‐5 Kashiwanoha Kashiwa Chiba 277‐8561 Japan
  • Takashi Uemura
    Department of Advanced Materials Science Graduate School of Frontier Sciences The University of Tokyo 5‐1‐5 Kashiwanoha Kashiwa Chiba 277‐8561 Japan

書誌事項

公開日
2020-03-19
資源種別
journal article
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#am
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/adma.201905657
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>Exploration of molecular functions and material properties based on the control of chirality would be a scientifically elegant approach. Here, the fabrication and function of chiral‐featured materials from both chiral and achiral components using a supramolecular nanoarchitectonics concept are discussed. The contents are classified in to three topics: i) chiral nanoarchitectonics of rather general molecular assemblies; ii) chiral nanoarchitectonics of metal–organic frameworks (MOFs); iii) chiral nanoarchitectonics in liquid crystals. MOF structures are based on nanoscopically well‐defined coordinations, while mesoscopic orientations of liquid‐crystalline phases are often flexibly altered. Discussion on the effects and features in these representative materials systems with totally different natures reveals the universal importance of supramolecular chiral nanoarchitectonics. Amplification of chiral molecular information from molecules to materials‐level structures and the creation of chirality from achiral components upon temporal statistic fluctuations are universal, regardless of the nature of the assemblies. These features are thus surely advantageous characteristics for a wide range of applications.</jats:p>

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