Chiral Bifunctional Selenide Catalysts for Asymmetric Bromolactonization

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  • Ryuichi Nishiyori
    Department of Environmental Science Graduate School of Fisheries and Environmental Sciences Nagasaki University 1–14 Bunkyo-machi Nagasaki 852-8521 Japan
  • John R. J. Maynard
    Department of Environmental Science Graduate School of Fisheries and Environmental Sciences Nagasaki University 1–14 Bunkyo-machi Nagasaki 852-8521 Japan
  • Seiji Shirakawa
    Department of Environmental Science Graduate School of Fisheries and Environmental Sciences Nagasaki University 1–14 Bunkyo-machi Nagasaki 852-8521 Japan

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<jats:title>Abstract</jats:title><jats:p>The development of chiral selenium catalysts for asymmetric transformations has become a pre‐eminent topic in the field of organocatalytic chemistry. Herein, we report the development of chiral bifunctional selenide catalysts bearing a hydroxy group and discuss their application to asymmetric bromolactonization reactions. The importance of the bifunctional design of chiral selenide catalysts for enantioselective bromolactonizations was clearly demonstrated in the present work.</jats:p>

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