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Catalytic C−H Borylation Using Iron Complexes Bearing 4,5,6,7‐Tetrahydroisoindol‐2‐ide‐Based PNP‐Type Pincer Ligand
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- Takeru Kato
- Department of Systems Innovation School of Engineering The University of Tokyo Bunkyo-ku Tokyo 113-8656 Japan
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- Shogo Kuriyama
- Department of Systems Innovation School of Engineering The University of Tokyo Bunkyo-ku Tokyo 113-8656 Japan
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- Kazunari Nakajima
- Frontier Research Center for Energy and Resources School of Engineering The University of Tokyo Bunkyo-ku Tokyo 113-8656 Japan
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- Yoshiaki Nishibayashi
- Department of Systems Innovation School of Engineering The University of Tokyo Bunkyo-ku Tokyo 113-8656 Japan
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Description
<jats:title>Abstract</jats:title><jats:p>Catalytic C−H borylation has been reported using newly designed iron complexes bearing a 4,5,6,7‐tetrahydroisoindol‐2‐ide‐based PNP pincer ligand. The reaction tolerated various five‐membered heteroarenes, such as pyrrole derivatives, as well as six‐membered aromatic compounds, such as toluene. Successful examples of the iron‐catalyzed sp<jats:sup>3</jats:sup> C−H borylation of anisole derivatives were also presented.</jats:p>
Journal
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- Chemistry – An Asian Journal
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Chemistry – An Asian Journal 14 (12), 2097-2101, 2019-05-17
Wiley
