Parent Cyclopentadienyl Ruthenium(II) Chloride Synthon: Derivatization to CpRu Amido, Imido, and Oxo Complexes

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  • Shin Takemoto
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
  • Hana Ishii
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
  • Masahiro Yamaguchi
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
  • Akira Teramoto
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
  • Masayuki Tsujita
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
  • Daiki Ozeki
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
  • Hiroyuki Matsuzaka
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan

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説明

The complex salt [CpRu(η6-C10H8)][(CpRu)2(μ-Cl)3] ([1][2]) was synthesized and found to be a useful CpRuCl synthon. The ions [1]+ and [2]− cleanly comproportionate into monomeric CpRuCl(L)2 complex...

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  • Organometallics

    Organometallics 38 (21), 4298-4306, 2019-10-15

    American Chemical Society (ACS)

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