Highly Ordered Mesoporous Carbon Nitride Nanoparticles with High Nitrogen Content: A Metal‐Free Basic Catalyst

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書誌事項

公開日
2009-09-30
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/anie.200903674
  • 10.1002/ange.200903674
公開者
Wiley

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説明

Nitrogen-rich carbon nitride is obtained as ultrasmall, discrete, mesoporous nanoparticles (see picture) by reaction of ethylenediamine with CCl in the nanochannels of a mesoporous silica template. Its high nitrogen content, large surface area, and large pore volume make it a highly active catalyst for transesterification of β-keto esters of aryl, aliphatic, and cyclic primary alcohols.

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