Single‐Junction Organic Photovoltaic Cells with Approaching 18% Efficiency

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  • Yong Cui
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China
  • Huifeng Yao
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China
  • Jianqi Zhang
    CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology Beijing 100190 China
  • Kaihu Xian
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China
  • Tao Zhang
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China
  • Ling Hong
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China
  • Yuming Wang
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China
  • Ye Xu
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China
  • Kangqiao Ma
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China
  • Cunbin An
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China
  • Chang He
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China
  • Zhixiang Wei
    University of Chinese Academy of Sciences Beijing 100049 China
  • Feng Gao
    Department of Physics Chemistry and Biology Linköping University Linköping Sweden
  • Jianhui Hou
    State Key Laboratory of Polymer Physics and Chemistry Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China

書誌事項

公開日
2020-03-29
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/adma.201908205
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>Optimizing the molecular structures of organic photovoltaic (OPV) materials is one of the most effective methods to boost power conversion efficiencies (PCEs). For an excellent molecular system with a certain conjugated skeleton, fine tuning the alky chains is of considerable significance to fully explore its photovoltaic potential. In this work, the optimization of alkyl chains is performed on a chlorinated nonfullerene acceptor (NFA) named BTP‐4Cl‐BO (a Y6 derivative) and very impressive photovoltaic parameters in OPV cells are obtained. To get more ordered intermolecular packing, the <jats:italic>n</jats:italic>‐undecyl is shortened at the edge of BTP‐eC11 to <jats:italic>n</jats:italic>‐nonyl and <jats:italic>n</jats:italic>‐heptyl. As a result, the NFAs of BTP‐eC9 and BTP‐eC7 are synthesized. The BTP‐eC7 shows relatively poor solubility and thus limits its application in device fabrication. Fortunately, the BTP‐eC9 possesses good solubility and, at the same time, enhanced electron transport property than BTP‐eC11. Significantly, due to the simultaneously enhanced short‐circuit current density and fill factor, the BTP‐eC9‐based single‐junction OPV cells record a maximum PCE of 17.8% and get a certified value of 17.3%. These results demonstrate that minimizing the alkyl chains to get suitable solubility and enhanced intermolecular packing has a great potential in further improving its photovoltaic performance.</jats:p>

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