Preparation and Properties of Metal Complexes with TTP-Dithiolate Ligands
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- Yohji Misaki
- a Department of Molecular Engineering, Graduate School of Engineering , Kyoto University , Yoshida, Kyoto , 606-8501 , Japan
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- Yoshihiro Tani
- a Department of Molecular Engineering, Graduate School of Engineering , Kyoto University , Yoshida, Kyoto , 606-8501 , Japan
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- Kazuyuki Takahashi
- a Department of Molecular Engineering, Graduate School of Engineering , Kyoto University , Yoshida, Kyoto , 606-8501 , Japan
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- Kazuyoshi Tanaka
- a Department of Molecular Engineering, Graduate School of Engineering , Kyoto University , Yoshida, Kyoto , 606-8501 , Japan
Description
Several copper and platinum complexes with TTP (2,5-bis(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene) dithiolato ligands, Cu(ttpdt) 2 ( 1 ) and Pt(ttpdt)(bpy) ( 2 ), have been prepared. The tetrakis(ethylthio) and tetrakis(hexylthio) derivatives of neutral Cu(ttpdt) 2 showed relatively high conductivity of rt =10 m 2 S cm m 1 on compressed pellets. On the other hand, radical cation salts of 1 and 2 exhibited moderate conductivity of rt =10 m 2 m 10 m 4 S cm m 1 . dithiolene complex tetrathiapentalene cyclic voltammetry electrical conductivity
Journal
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- Molecular Crystals and Liquid Crystals
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Molecular Crystals and Liquid Crystals 379 (1), 71-76, 2002-01-01
Informa UK Limited
