Diacetylenic Lipid Tubules: Experimental Evidence for a Chiral Molecular Architecture

  • J. M. Schnur
    Center for Bio/Molecular Science and Engineering, Naval Research Laboratory, Washington, DC 20375, USA.
  • B. R. Ratna
    Center for Bio/Molecular Science and Engineering, Naval Research Laboratory, Washington, DC 20375, USA.
  • J. V. Selinger
    Center for Bio/Molecular Science and Engineering, Naval Research Laboratory, Washington, DC 20375, USA.
  • A. Singh
    Center for Bio/Molecular Science and Engineering, Naval Research Laboratory, Washington, DC 20375, USA.
  • G. Jyothi
    Molecular Biophysics Unit, Indian Institute of Science, Bangalore 560012, India
  • K. R. K. Easwaran
    Molecular Biophysics Unit, Indian Institute of Science, Bangalore 560012, India

書誌事項

公開日
1994-05-13
DOI
  • 10.1126/science.264.5161.945
公開者
American Association for the Advancement of Science (AAAS)

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説明

<jats:p>Molecular self-assembly is of key importance for the rational design of advanced materials. To investigate the causal relation between molecular structure and the consequent self-assembled microstructure, self-assembled tubules of diacetylenic lipids were studied. Circular-dichroism studies give experimental evidence that the formation of tubules is driven by chiral molecular packing, in agreement with recent theories of tubules. On the basis of these results, a molecular mechanism for the formation of tubules is proposed.</jats:p>

収録刊行物

  • Science

    Science 264 (5161), 945-947, 1994-05-13

    American Association for the Advancement of Science (AAAS)

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