Diacetylenic Lipid Tubules: Experimental Evidence for a Chiral Molecular Architecture
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- J. M. Schnur
- Center for Bio/Molecular Science and Engineering, Naval Research Laboratory, Washington, DC 20375, USA.
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- B. R. Ratna
- Center for Bio/Molecular Science and Engineering, Naval Research Laboratory, Washington, DC 20375, USA.
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- J. V. Selinger
- Center for Bio/Molecular Science and Engineering, Naval Research Laboratory, Washington, DC 20375, USA.
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- A. Singh
- Center for Bio/Molecular Science and Engineering, Naval Research Laboratory, Washington, DC 20375, USA.
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- G. Jyothi
- Molecular Biophysics Unit, Indian Institute of Science, Bangalore 560012, India
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- K. R. K. Easwaran
- Molecular Biophysics Unit, Indian Institute of Science, Bangalore 560012, India
書誌事項
- 公開日
- 1994-05-13
- DOI
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- 10.1126/science.264.5161.945
- 公開者
- American Association for the Advancement of Science (AAAS)
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説明
<jats:p>Molecular self-assembly is of key importance for the rational design of advanced materials. To investigate the causal relation between molecular structure and the consequent self-assembled microstructure, self-assembled tubules of diacetylenic lipids were studied. Circular-dichroism studies give experimental evidence that the formation of tubules is driven by chiral molecular packing, in agreement with recent theories of tubules. On the basis of these results, a molecular mechanism for the formation of tubules is proposed.</jats:p>
収録刊行物
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- Science
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Science 264 (5161), 945-947, 1994-05-13
American Association for the Advancement of Science (AAAS)
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詳細情報 詳細情報について
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- CRID
- 1361699994674036992
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- NII論文ID
- 30020548720
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- ISSN
- 10959203
- 00368075
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