Thermal expansion of CuMoO<sub>4</sub> below room temperature

書誌事項

公開日
1998-04-01
DOI
  • 10.1524/zkri.1998.213.4.210
公開者
Walter de Gruyter GmbH

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説明

<jats:title>Abstract</jats:title> <jats:p>Structure data for both triclinic <jats:italic>α</jats:italic>- and <jats:italic>γ</jats:italic>-CuMoO<jats:sub>4</jats:sub> have been delivered with anisotropic temperature factors at 190 K. The complete tensors of linear thermal expansion coefficients were derived for <jats:italic>α</jats:italic>- and <jats:italic>γ</jats:italic>-CuMoO<jats:sub>4</jats:sub> using the temperature dependence of lattice parameters within the temperature range 20 K–300 K and 20 K–260 K, respectively. The orientation of principal axes and values of principal expansion coefficients are given for selected temperatures. Their relation to the structure is discussed. The volume expansion coefficient of <jats:italic>α</jats:italic>-CuMoO<jats:sub>4</jats:sub> becomes negative below 80 K.</jats:p>

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