Physical properties of liquid Fe alloys at high pressure and their bearings on the nature of metallic planetary cores

  • C. Sanloup
    Laboratoire de Sciences de la Terre, Ecole Normale Supérieure de Lyon Lyon France
  • F. Guyot
    Laboratoire de Minéralogie‐Cristallographie Physique and Institut de Physique du Globe de Paris Paris France
  • P. Gillet
    Laboratoire de Sciences de la Terre, Ecole Normale Supérieure de Lyon Lyon France
  • Y. Fei
    Geophysical Laboratory and Center for High Pressure Research Carnegie Institution of Washington, D. C. USA

書誌事項

公開日
2002-11
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1029/2001jb000808
公開者
American Geophysical Union (AGU)

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説明

<jats:p>Sulfur and silicon are among the expected alloying light elements in planetary liquid iron cores. Structural properties of Fe‐27 wt % S and Fe‐17 wt % Si liquid alloys at high pressure and high temperature (0–5 GPa/1400–2300 K) are measured by synchrotron X‐ray diffraction. Sulfur strongly modifies the local structure of liquid iron whereas silicon has only small structural effects. Fe‐27 wt % S melts are indeed poorly ordered which explains a higher compressibility compared to pure liquid Fe. These results point out the necessity to consider the strong effect of S on liquid Fe properties while modeling planetary interiors. They imply a low S content in the Earth's outer core, leaving Si as a strong candidate, and argue for a present‐day Martian solid core when combined with previous global chemical models.</jats:p>

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