Phosphole-Containing Hybrid Calixpyrroles:  New Multifunctional Macrocyclic Ligands for Platinum(II) Ions

DOI HANDLE Web Site 研究データあり 被引用文献2件
  • Yoshihiro Matano
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan
  • Takashi Nakabuchi
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan
  • Tooru Miyajima
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan
  • Hiroshi Imahori
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan
  • 90243261

書誌事項

公開日
2006-05-17
DOI
  • 10.1021/om060300a
公開者
American Chemical Society (ACS)

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説明

Phosphole-containing hybrid calixpyrroles have been prepared by acid-promoted condensation reactions. σ3-Calix[1]phosphole[1]thiophene[2]pyrrole reacts with PtCl2(COD) to afford an unusual type of macrocyclic Pt(II)−monophosphine complex bearing a η3-cyclooctadienyl ligand, in which the phosphole and pyrrole units bind the Pt−Cl moiety through cooperative, noncovalent bonding interactions.

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  • Organometallics

    Organometallics 25 (13), 3105-3107, 2006-05-17

    American Chemical Society (ACS)

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