Purification and characterisation of 6G-fructosyltransferase from the roots of asparagus (Asparagus officinalis L.)

書誌事項

公開日
1981-10
権利情報
  • https://www.elsevier.com/tdm/userlicense/1.0/
DOI
  • 10.1016/s0008-6215(00)81878-9
公開者
Elsevier BV

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説明

Abstract A fructosyltransferase that transfers a terminal d -fructosyl group from a (2→1)-β-linked fructosaccharide to HO-1 of another d -fructosyl group has been purified from an extract of asparagus roots by successive chromatography with DEAE-cellulose, octyl-Sepharose, Sephadex G-200, and raffinose-coupled Sepharose 6B. The disc-electrophoretically homogeneous enzyme was free from β- d -fructofuranosidase, sucrose:sucrose 1-fructosyltransferase, and 6G-frutosyltransferase activity, and catalysed the d -fructosyl transfer from 1-kestose more rapidly to saccharides of the neokestose series [1F(1-β- d -fructofuranosyl)m-6G(1-β- d -fructofuranosyl)nsucrose] than to those of the 1-kestose series [1F(1-β- d -fructofuranosyl)nsucrose]. The enzyme was tentatively termed 1F-fructosyltransferase. The general properties of the enzyme were as follows: mol. wt., ~64,000; optimum pH, ~5.0; stable at pH 5.0–5.5 at 45° for 20 min; stable at 30–45° for 10 min; inhibited by Hg2+, p-chloromercuribenzoate, and Ag+.

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