Synthesis and characterization of N-confused porphyrinatoantimony(V): toward a low energy gap molecular wire
書誌事項
- 公開日
- 2000-10
- 権利情報
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- https://www.elsevier.com/tdm/userlicense/1.0/
- https://www.elsevier.com/legal/tdmrep-license
- DOI
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- 10.1016/s0022-328x(00)00405-8
- 公開者
- Elsevier BV
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説明
N-Confused tetraarylporphyrinatoantimony(V) dimethoxides were synthesized and their X-ray crystallographic structure, absorption spectra and voltammetric spectra were studied. X-ray crystallographic structure revealed neutral molecules with no counter anion. From the absorption spectra and voltammetric studies we estimated their energy gaps to be about 0.2 eV less than the corresponding porphyrinatoantimony(V). The axial ligands could easily be exchanged in solvent alcohol by acid promotion. These characteristics of N-confused porphyrinatoantimony(V) indicate that they are good candidates for the molecular wire component.
収録刊行物
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- Journal of Organometallic Chemistry
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Journal of Organometallic Chemistry 611 (1-2), 551-557, 2000-10
Elsevier BV