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- Xinjun Tang
- Westfälische Wilhelms-Universität Organisch-Chemisches Institut Corrensstraße 40 48149 Münster Germany
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- Armido Studer
- Westfälische Wilhelms-Universität Organisch-Chemisches Institut Corrensstraße 40 48149 Münster Germany
書誌事項
- 公開日
- 2017-12-14
- 権利情報
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- http://creativecommons.org/licenses/by-nc-nd/4.0/
- DOI
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- 10.1002/anie.201710397
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>Transition‐metal‐free radical α‐perfluoroalkylation with the accompanying vicinal β‐alkenylation of unactivated alkenes is presented. These radical cascades proceed by means of 1,4‐ or 1,5‐alkenyl migration by electron catalysis on readily accessed allylic alcohols. The reactions comprise a regioselective perfluoroalkyl radical addition with subsequent alkenyl migration and concomitant deprotonation to generate a ketyl radical anion that sustains the chain as a single‐electron‐transfer reducing reagent.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 57 (3), 814-817, 2017-12-14
Wiley