Synthesis of Nitrogen‐Containing Rubicene and Tetrabenzopentacene Derivatives
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- Young S. Park
- Department of Chemical Engineering and Materials Science University of California, Irvine Irvine CA 92697 USA
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- David J. Dibble
- Department of Chemical Engineering and Materials Science University of California, Irvine Irvine CA 92697 USA
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- Juhwan Kim
- Department of Chemical Engineering and Materials Science University of California, Irvine Irvine CA 92697 USA
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- Robert C. Lopez
- Department of Chemistry University of California, Irvine Irvine CA 92697 USA
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- Eriberto Vargas
- Department of Chemical Engineering and Materials Science University of California, Irvine Irvine CA 92697 USA
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- Alon A. Gorodetsky
- Department of Chemical Engineering and Materials Science University of California, Irvine Irvine CA 92697 USA
書誌事項
- 公開日
- 2016-02-02
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/anie.201510320
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>Carbon‐based materials, such as acenes, fullerenes, and graphene nanoribbons, are viewed as the potential successors to silicon in the next generation of electronics. Although a number of methodologies provide access to these materials’ all‐carbon variants, relatively fewer strategies readily furnish their nitrogen‐doped analogues. Herein, we report the rational design, preparation, and characterization of nitrogen‐containing rubicenes and tetrabenzopentacenes, which can be viewed either as acene derivatives or as molecular fragments of fullerenes and graphene nanoribbons. The reported findings may prove valuable for the development of electron transporting organic semiconductors and for the eventual construction of larger carbonaceous systems.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 55 (10), 3352-3355, 2016-02-02
Wiley