Assignment of ν2 (<i>E</i>) and ν4 (<i>F</i>2) of tetrahedral species by the calculation of the relative Raman intensities: The vibrational spectra of VO43−, CrO42−, MoO42−, WO42−, MnO4−, TcO4−, ReO4−, RuO4, and OsO4

DOI PDF 被引用文献3件
  • N. Weinstock
    Institute of Chemistry, University of Göttingen, 3400 Göttingen, Germany
  • H. Schulze
    Institute of Chemistry, University of Göttingen, 3400 Göttingen, Germany
  • A. Müller
    Institute of Chemistry, University of Dortmund, 46 Dortmund, Germany

書誌事項

公開日
1973-11-01
DOI
  • 10.1063/1.1680724
公開者
AIP Publishing

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<jats:p>A new method has been developed to assign the frequencies ν2(E) and ν4(F2) in tetrahedral molecules and ions. The method employs the calculation of the relative Raman intensities and has been applied to VO43−, CrO42−, MoO42−, WO42−, MnO4−, TcO4−, ReO4−, RuO4, and OsO4. The assignment of the frequencies has been further confirmed by measuring the infrared and Raman spectra of some of the ions and molecules in the same solvent. A more complete spectrum of TcO4− than earlier reported in the literature has been given.</jats:p>

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