Weakly Coordinating Directing Groups for Ruthenium(II)‐ Catalyzed CH Activation

Suman De Sarkar, Weiping Liu, Sergei I. Kozhushkov, Lutz Ackermann

doi:10.1002/adsc.201400110

Weakly Coordinating Directing Groups for Ruthenium(II)‐ Catalyzed CH Activation

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書誌事項

公開日: 2014-04-30

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http://onlinelibrary.wiley.com/termsAndConditions#vor

DOI

10.1002/adsc.201400110

公開者: Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>Synthetically useful functional groups, including ketones, amides, carbamates, carboxylic acids, aldehydes or ethers, have been identified as weakly coordinating directing groups in efficient ruthenium(II)‐catalyzed CH functionalizations. This strategy set the stage for versatile CH bond olefinations, oxygenations, nitrogenations and oxidative alkyne annulations among others. Thereby, step‐economical access to diversely decorated arenes and heteroarenes was provided in a sustainable fashion.</jats:p><jats:p><jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/gif" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/mcontent.gif"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p>