Cubane Chirality via Substitution of a “Hidden” Regular Tetrahedron

  • Nana Yoshino
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-Katsura, Nishikyo, Kyoto 615-8510, Japan
  • Yumi Kato
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-Katsura, Nishikyo, Kyoto 615-8510, Japan
  • Thibaud Mabit
    JSPS International Fellowship for Research, Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-Katsura, Nishikyo, Kyoto 615-8530, Japan
  • Yuuya Nagata
    Institute for Chemical Reaction Design and Discovery, Hokkaido University, Nishi 10, Kita, Sapporo 001-0021, Japan
  • Craig M. Williams
    School of Chemistry and Molecular Biosciences, University of Queensland, Brisbane, Queensland 4072, Australia
  • Mei Harada
    Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
  • Atsuya Muranaka
    Cluster of Pioneering Research (CPR), Advanced Elements Chemistry Laboratory, RIKEN, 2-1 Hirosawa, Wako-shi, Saitama 351-0198, Japan
  • Masanobu Uchiyama
    Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
  • Seijiro Matsubara
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-Katsura, Nishikyo, Kyoto 615-8510, Japan

書誌事項

公開日
2020-05-21
資源種別
journal article
権利情報
  • https://doi.org/10.15223/policy-029
  • https://doi.org/10.15223/policy-037
  • https://doi.org/10.15223/policy-045
DOI
  • 10.1021/acs.orglett.0c01142
公開者
American Chemical Society (ACS)

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説明

In the hexahedral hydrocarbon cubane, replacing hydrogen with other atoms at three positions within any one of the internal tetrahedrons can conceptually lead to the formation of a unique class of chiral molecules. In pursuit of this endeavor, we prepared 1,3-dibromo-4-deuteriocubane-

収録刊行物

  • Organic Letters

    Organic Letters 22 (11), 4083-4087, 2020-05-21

    American Chemical Society (ACS)

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