Increasing the work function of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) by ultraviolet irradiation

  • Yow-Jon Lin
    National Changhua University of Education Institute of Photonics, , Changhua 500, Taiwan
  • Fu-Ming Yang
    National Changhua University of Education Institute of Photonics, , Changhua 500, Taiwan
  • Chi-Yen Huang
    National Changhua University of Education Institute of Photonics, , Changhua 500, Taiwan
  • Wei-Yang Chou
    National Cheng Kung University Institute of Electro-Optical Science and Engineering, , Tainan 701, Taiwan
  • Jay Chang
    National Cheng Kung University Institute of Electro-Optical Science and Engineering, , Tainan 701, Taiwan
  • Yi-Chun Lien
    National Changhua University of Education Department of Physics, , Changhua 500, Taiwan

書誌事項

公開日
2007-08-27
DOI
  • 10.1063/1.2777147
公開者
AIP Publishing

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説明

<jats:p>The effects of ultraviolet (UV) irradiation on the work function of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) (PEDOT:PSS) have been investigated in this study. Spectroscopic methods [x-ray photoelectron spectroscopy and Raman spectroscopy (532nm excitation)] and electrical conductivity measurements were used to characterize the electrical conducting polymer PEDOT:PSS prepared by UV irradiation. The authors found that UV irradiation could lead to an increase in the work function and the enhancement of electrical conductivity of PEDOT:PSS, resulting from a decrease in the number of the charge-trapping-related defects and the formation of linear or expanded-coil conformation.</jats:p>

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