Tunnelling Model for Quasi‐One‐Dimensional Hydrogen‐Bonded Crystals

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<jats:title>Abstract</jats:title><jats:p>Tunnelling term is included in the Hamiltonian of an anisotropic Ising model which is used to explain the thermodynamic properties of quasi‐one‐dimensional hydrogen‐bonded ferroelectric crystals. A variational approach is used to treat the strong intrachain interactions accurately, while the weak interchain interactions are accounted for in a mean‐field approximation. Also, fittings are presented of some experimental data pertaining to crystals of PbHPO<jats:sub>4</jats:sub>.</jats:p>

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