Synthesis and preliminary use of naphthyl quinazoline and isoquinoline oxazolines for asymmetric allylic oxidation
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説明
<jats:title>Abstract</jats:title><jats:p>This paper is dedicated to Professor Jerald S. Bradshaw, undergraduate mentor of MBA, with warmth and gratitude for his encouragement and outstanding leadership.</jats:p><jats:p>Four new oxazoline ligands, 4‐naphthyl‐2‐phenylquinazoline 4 and 1‐naphthylisoquinoline 5 were made using Suzuki coupling, a Pictet‐Gams reaction, and <jats:italic>S</jats:italic>‐amino alcohol. Preliminary use as ligands for asymmetric copper catalyzed allylic oxidation with cyclohex‐ene and perester showed promise providing <jats:italic>S</jats:italic>‐cyclohexenyl benzoate product in moderate enantioselectivity (64%ee).</jats:p>
収録刊行物
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- Journal of Heterocyclic Chemistry
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Journal of Heterocyclic Chemistry 38 (6), 1265-1271, 2001-11
Wiley