Synthesis and properties of TTP analog with a cyclohexene ring inserted

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A new tetrathiapentalene (TTP) type donor, 2-(2-cyclohexenediylidene-1,3- dithiole)-5-(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene (CHDTDT), has been prepared. Cyclic voltammogram of CHDTDT showed three pairs of redox waves at 0.00 (2e), +0.42 (1e) and +0.66 (1e) V (vs. Ag/Ag + , in PhCN). CHDTDT has yielded several metallic radical cation salts. Among them, the AsF 6 salt exhibited metallic conductivity down to 4.2 K.

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