Ferroelectric poly(vinylidene fluoride) thin films on Si substrate with the β phase promoted by hydrated magnesium nitrate
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- Shuting Chen
- National University of Singapore Department of Mechanical Engineering, , 119260 Singapore and (IMRE), 3 Research Link, 117602 Singapore
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- Kui Yao
- Institute of Materials Research and Engineering (IMRE), 3 Research Link, 117602 Singapore
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- Francis Eng Hock Tay
- National University of Singapore Department of Mechanical Engineering, , 119260 Singapore
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- Chung Lee Liow
- Institute of Materials Research and Engineering (IMRE), 3 Research Link, 117602 Singapore
書誌事項
- 公開日
- 2007-11-15
- DOI
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- 10.1063/1.2812702
- 公開者
- AIP Publishing
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説明
<jats:p>Solution derived poly(vinylidene fluoride) (PVDF) homopolymer thin films on silicon substrates with the addition of hydrated salt [Mg(NO3)2⋅6H2O] were systematically investigated. β phase dominant ferroelectric PVDF thin films with a remnant polarization of 77 mC∕m2 were achieved by optimizing the concentration of Mg(NO3)2⋅6H2O and the processing condition. Our experimental results and theoretical analysis indicated that the hydrogen bonds between water in the hydrated salt and the PVDF molecules result in the interchain registration of the all-trans conformation, and the hydrated salt acts as the nucleation agent and promotes the crystallization of the β phase. The obtained effective d33 was −14.5 pm∕V, tested with a laser scanning vibrometer, without taking into account the substrate clamping effect. The numerical simulation, after considering the elastic constrain of the substrate, determined that the corresponding actual d33 is −30.8 pm∕V, which is comparable to that of uniaxially stretched piezoelectric PVDF films.</jats:p>
収録刊行物
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- Journal of Applied Physics
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Journal of Applied Physics 102 (10), 104108-, 2007-11-15
AIP Publishing